چكيده لاتين :
Novel polyoxometalate-based organic-inorganic hybrid [NH3-CH(CH3)COOH][H3O]8[PMo12O40]3.4NH3CH(CH3)COO was
synthesized and characterized by 31P, 1H, 13C NMR and IR spectroscopies, elemental analysis and single crystal X-ray
determination. Two of the PMo12O40
3- anions in the title hybrid are symmetrically equivalent. They are crystallographically
independent from the third PMo12O40
3- polyoxoanion, in the case of various interactions with neighboring components in the
crystal network (i.e. +NH3-CH(CH3)-COOH and H3O+ cations, +NH3CH(CH3)COO- zwitterions and polyoxoanions). The
compound crystallizes in an orthorhombic C222 space group with a = 16.0392(16) إ, b = 34.480(4) إ, c = 12.8968(13) إ and Z
= 2.
