چكيده لاتين :
The objectives of this study were to identify the chlorinated volatile organic compounds near the water
surface of two heavily polluted rivers in the south of Taiwan and compare their concentration distributions. Air samples
were collected seasonally at the upstream, midstream and downstream water surfaces of each river and the chlorinated
volatile organic compounds were analyzed qualitatively and quantitatively by gas chromatography and electron capture
detector. Totally, twelve kinds of chlorinated volatile organic compounds were found at the water surfaces of both rivers
and many of them were reported to be carcinogenic or probably carcinogenic to human. The results showed that each
chlorinated volatile organic compound had its own distribution pattern and no good correlation of chlorinated volatile
organic compounds between both rivers was obtained. The chlorinated volatile organic compounds identified at the river
water surface of Fong Shan Stream showed much higher concentration than those of Chuen-Tsen River. Several chlorinated
volatile organic compounds, including chlorodibromomethane, hexachlorobutadiene, 1,1,2,2-tetrachloroethene and 1,2-
dibromo-3-chloropropane were found with much higher concentration (mean concentrations of 124.5 ىg/m3, 334.5 ىg/
m3, 92.2 ىg/m3, 268.4 ىg/m3, respectively) at the water surface of Fong Shan Stream in some seasons (especially spring
and summer, summer and winter, spring and winter, spring and summer, respectively) and they were reported to be
possibly carcinogenic to human. Therefore, it may be concluded that the people living close to Fong Shan Stream
possibly had higher health risks due to the release of volatile organic compounds from the heavily polluted river.