شماره ركورد :
44607
عنوان مقاله :
Synthesis, Characterization of some Transition metal complexes of Piperidine dithiocarbamate and ethylenediamine
پديد آورندگان :
mohammed, hasan.a. university of kirkuk - college of science - department of chemistry, iraq
از صفحه :
1
تا صفحه :
18
چكيده فارسي :
Piperidine is heterocyclic amine used as starting material for preparation piperidine dithiocarbamate (pipdtc).add the some transition metal salt of this ligand with ethylinediamine gave complexes of the types:[M(pipdtc)2en], [M(pipdtc)3] when the ratio, (M: pipdtc:en,1:2:1), ( M: pipdtc.1:3) respectively . The ligand dithiocarbamate (pipdtc) behaves as a bidentate and coordinated to the metal ion centers either through sulfur atoms and through nitrogen atoms of the ethylenediamine All the synthesized ligand and complexes are characterized by elemental analyses, conductivity, infrared, electronic spectra and susceptibility measurements and theoretical Calculations . From the obtained data octahedral geometry for the complexes have been suggested.
كليدواژه :
piperidine , dithiocarbamate , complexes , ethylenediamine
عنوان نشريه :
Kirkuk University Journal: Scientific Studies
لينک به اين مدرک :
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