كليدواژه :
Methanol production , process conditions , optimization , simulation
چكيده لاتين :
The production of Methanol from natural gas feedstock is one of the most
important gas-to-liquid processes which can be divided into four main stages: feed
purification, reforming, methanol synthesis and methanol purification. The light
ends present in the raw methanol are removed in the topping column. The
stabilized raw methanol consisting of methanol, water and minor amounts of
higher alcohols is fractionated in the purification section to produce methanol
grade AA.The optimization of the purification section is the subject of the present
work.The goal is to maximize the amount of final MeOH of AA gradein which,the
concentration of methanol is above 99.85(%wt).The simulation program Aspen
Plus®, was used to construct the process model and optimize the product
specifications. The effect ofdifferent parameters to optimize the columns of the
purification section has been investigated, such as thechange in reboiler duty, the
feed stage and the off gas temperature for thetopping column, whilereflux ratio,
side stream flow rateand reboiler duty are the variables which have been
optimized in therecovery column.According to the simulation, the total
methanolloss of 432.814kg/hr was estimated and with optimum conditions the
amount of methanol in the final product was 209115.74 kg/hr. The optimized
distillate rate and reboiler duty of the topping columnare 79.8 (kmol/hr) and
38.83481(MMkcal/hr), respectively. The optimumreflux ratioofthe recovery
columnwas obtainedwhich is2.23.