چكيده فارسي :
Palladium is the most widely utilized catalysts for the formation of C−S, C−N and C−C bonds in both industry and academia ]1[. Alloying is a strategy that has been used to find non-Pd catalysts that are effective and less expensive for the Suzuki-Miyaura cross-coupling ]2[. Pd/CdS nanoparticles (NPs) thin film was synthesized by the reduction of an organopalladium(II) complex, [PdCl2(cod)] (cod = cis,cis-1,5-cyclooctadiene) and a semiconductor of CdS at an oil–water interface. The structure and morphology of the as-prepared NPs was characterized with X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of the prepared NPs was investigated in the Suzuki–Miyaura cross-coupling reaction in H2O. Pd/CdS thin filmexhibited higher catalytic activity compared to Pd thin film in the Suzuki–Miyaura coupling reaction due to the appropriate interaction between palladium and CdS.Comparedto the classical reactions, this method consistently has the advantages of a green solvent, low catalyst loading, short reactiontimes, high yields and reusability of the catalyst.
