شماره ركورد كنفرانس :
3776
عنوان مقاله :
PdCuFe/reduced-graphene oxide nanohybrid thin film at oil/water interface suitable for catalytic reduction of p-nitrophenol
پديدآورندگان :
Aramesh Nahal YasoujUniversity , Hoseini S Jafar jhosseini@yu.ac.ir YasoujUniversity
تعداد صفحه :
1
كليدواژه :
,
سال انتشار :
1395
عنوان كنفرانس :
بيست چهارمين سمينار شيمي آلي ايران
زبان مدرك :
انگليسي
چكيده فارسي :
The oil/waterinterfacial assembly strategy provides a powerful bottom-up approach for the nanofilm fabrication due to low cost and low environmental impact [1]. Most importantadvantages of this assembly strategy are the significant simplicity and universality found in almost all of the related low dimensional nanostructures. Recently, this techniquehas been used for the preparation of metal, semiconductor and oxide nanocrystals [2]. The method used to prepare thin films at the organic-aqueous interface involves dissolving the relevant precursor in the organic layer and injecting an appropriate reagent in the aqueous layer.Graphene oxide (GO) is widely usedas excellent carbon support for catalysts to achieve the desired activity and stability. It has been reported that graphene/GO-supported metal or metal oxide nanoparticles (NPs) could improve the performance of catalysts in the different ofreaction [3]. In this work, PdCuFe/RGO thin film was synthesized by the reduction of [PdCl2(cod)], [Cu(acac)2] and [Fe(acac)3] complexes as palladium, copper and iron precursors at the toluene-water interface. The nanohybrid was characterized by X-ray diffraction (XRD), energy-dispersive analysis of X-ray (EDAX) and Transmissionelectron microscopy (TEM). Then we investigated the catalytic activityproperty of this nanostructure in the reduction reaction of p-nitrophenol.
كشور :
ايران
لينک به اين مدرک :
بازگشت