شماره ركورد كنفرانس :
3834
عنوان مقاله :
A STUDY OF CONVERSION OF ISOMER KINETICALLY TO ISOMER THERMODYNAMICALLY WITH TECHNIQUE NMR
پديدآورندگان :
Azami Fatemeh shahnaz_azami@yahoo.com Department of Chemistry, Faculty of Science, University of Tehran, Tehran, Iran;
كليدواژه :
isomer , thermodynamically , NMR technique , , carbamate , kinethically
عنوان كنفرانس :
نوزدهمين سمينار شيمي فيزيك ايران
چكيده فارسي :
Reaction of carbamate with DMF gives rise two isomers .The process was followered employing the NMR technique,removing samples in different time in tervals. The percentage yields were obtained and potted vs time exhibting a logarithmic reaction ship. isomer (B) .scheme appears to be more, stale due to resonance factors.Although isomer (A) is kinethically more feasible . Spectral analysis is in accord with the above propositions
