SYNTHESIS NANO PARTICLES OF COPOLYMER FOR THE REMOVAL OF ALUMINIUM (III) IONS FROM AQUEOUS SOLUTIONS BY USING DERIVATE POLY (STYRENE ALTERNATIVE MALEIC ANHYDRIDE)

Synthesis of copolymers such as CSMA-MP that derivate from poly(styrene alternative maleic anhydride) SMA copolymer. Adsorption of Al (III) ions on modified SMA with melamine and modified melamine with propanedioic acid modified poly(styrene alternative maleic anhydride) cross linked by1,3-diamino propane(CSMA-MP) as an ion substitution resin has been studied in aqueous solution. Adsorption behavior of this Al (III) ions on the resin was studied by altering the characters such as pH (2–8), adsorbent dose (20-300 mg ), contact time (0–600 min), and Al (III) ions concentration (0-4g/L). Adsorption percentage was increased by increasing each of these parameters. Chelating resin has been purposed to be appropriate materials for the recovery of heavy metals in water remedies. The isotherm models such as: Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich were applied to explain adsorption equilibrium. The outcomes shown that the best match was accessed with the Langmuir isotherm equation, production maximum adsorption capacity of 94.63 mg/g with CSMA-MP resin for Al (III). The resin was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction analysis.