شماره ركورد كنفرانس :
4689
عنوان مقاله :
Synthesis, characterization of MOF-derived carbon Nano structures and their catalytic and conductivity studies
پديدآورندگان :
Naghiloo Mina University of Zanjan , Tarasi Somayeh Tarbiat Modares University , Rasuli Reza r_rasuli@znu.ac.ir University of Zanjan , Morsali Ali Morsali_a@modares.ac.ir Tarbiat Modares University
كليدواژه :
metal–organic frameworks , catalytic , conductivity.
عنوان كنفرانس :
اولين كنفرانس ملي كاتاليست ايران
چكيده فارسي :
In the past decade, metal−organic frameworks (MOFs) have attracted considerable interest because of their potential applications in different fields such as catalysis, gas storage, and sensing [1]. This interest is largely based on the ability to tailor the topology, pore size, and functionality by judicious selection of the molecular building blocks. A porous Zn(II)-based metal–organic frameworks, PG/TMU-21(RL2), containing Amin-functionalized pores, were readily and quickly prepared via mechanosynthesis. The structure of this framework has been determined further characterized by Fourier transform infrared spectroscopy and Thermogravimetric analysis. A catalytic performance and conductivity study of these MOF is investigated. Results show that among the similar compounds, PG/TMU-21(RL2) with BET 3,375.21 m²/g has the highest catalytic activity. These catalysts maintain their crystalline framework after the reaction and are easily recycled.