چكيده فارسي :
Metal-organic frameworks (MOFs) are formed by reticular synthesis, which creates
strong bonds between inorganic and organic units The flexibility with which the constituents, geometry, size, and functionality can be varied has led to more than 20,000 different MOFs being reported and studied within the past decade. The surface area values of such MOFs typically range from 1000 to 10,000 m2/g, thus exceeding those of traditional porous materials such as zeolites and carbons. The extraordinary skeleton structure of MOFs provides many possibilities for incorporation of diverse basic functionalities, which is unachievable for conventional solid base. These aspects have made MOFs ideal candidates for storage of fuels (hydrogen and methane), capture of carbon dioxide, and catalysis applications.These solid bases have potential to catalyze some well-known “base-catalyzed reactions” like Knoevenagel condensation, aldol condensation, and Michael addition. Meanwhile, in contrast to conventional solid bases, MOFs show some different catalytic properties due to their special structural and surface properties. In this paper we provide a comprehensive review of MOFs derived solid bases, summarizing recent advances from various research groups.
