شماره ركورد كنفرانس :
4689
عنوان مقاله :
Shape Control of Zn(II) Metal–Organic Frameworks by Modulation Synthesis and Their Morphology-Dependent Catalytic Performance
پديدآورندگان :
Rafizadeh Masuleh Fatemeh Tarbiat Modares University , Masoomi Mohammad Yaser Tarbiat Modares University , Morsali Ali morsali_a@modares.ac.ir Tarbiat Modares University
كليدواژه :
Metal , Organic Frameworks , MOF , Catalysis
عنوان كنفرانس :
اولين كنفرانس ملي كاتاليست ايران
چكيده فارسي :
Micro- and nanorods and plates of three porous Zn(II)-based metal−organic frameworks, [Zn2(oba)2(4-bpdb)]n•2(DMF) (TMU-4), [Zn(oba)(4-bpdh)0.5]n•1.5(DMF) (TMU-5), and [Zn(oba)(4-bpmb)0.5]n 1.5(DMF) (TMU-6) were synthesized by the coordination modulation method. The effects of concentration of modulator, temperature, and time of reaction on size and morphology have been investigated. Also, catalytic performance of TMU-5 nanosized metal−organic framework in Knoevenagel condensation reaction was evaluated.
