پديدآورندگان :
Esrafili Leili leiliesrafili@gmail.com Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran, , Morsali Ali Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran
چكيده فارسي :
Two pillared metal-organic frameworks containing urea functional groups were synthesized by a sonochemical method and characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analysis. The time of sonication and concentration of starting materials have been optimized to synthesize nanoparticles of TMU-31 and TMU-32. These two frameworks are interesting candidates for a comparative fluorescence study. Thus, their potential abilities for phenol sensing were investigated. This investigation revealed the prominent roles of hydrogen bond donating urea groups inside the pore cavity in the ability of these structures in phenol sensing.