Author/Authors
Bahçeli, Semiha Süleyman Demirel University - Faculty of Arts and Sciences - Department of Physics, Turkey , Öztürk, Nuri Süleyman Demirel University - Faculty of Arts and Science - Department of Physics, Turkey , Akduman, Ümran Uygun Süleyman Demirel University - Faculty of Arts and Science - Department of Physics, Turkey
Title Of Article
The FT-IR Spectroscopic Investigation on Cd(II) and Co(II) Transition Metals 1,5-pentanedithiol and 1,8-octanedithiol Tetracyanonickelate Complexes
شماره ركورد
35951
Abstract
FT-IR spectra of the ligands, 1,5-pentanedithiol (PDT) and 1,8-octanedithiol (ODT), with their complexes with the divalent transition metal ions Co(II) and Cd(II) are reported for the first time in the 400-4000 cm^-1 range. Furthermore the thermal behaviors of M(PDT)Ni(CN)4 and M(ODT)Ni(CN)4 (M = Co and Cd) compounds were studied by thermo-gravimetric analysis (TGA), differential thermal analysis (DTA) and derivative thermal gravimetric analysis (DTG) in the range of (25-250) °C and their XRD patterns and elemental analyses were presented. The spectral and thermal features suggest that the compounds are similar in structure to the Hofmann-type complexes with infinite polymeric layers formed with Ni(CN)4 -2 ions bridged by ML^+2 cations.
From Page
99
NaturalLanguageKeyword
FT , IR , 1 , 5 , pentanedithiol , 1 , 8 , octanedithiol , Tetracyanonickelate , Thermal analysis
JournalTitle
Süleyman Demirel University Faculty of Arts and Science Journal of Science
To Page
111
JournalTitle
Süleyman Demirel University Faculty of Arts and Science Journal of Science
Link To Document