• DocumentCode
    1050836
  • Title

    Electrical conductivity of seawater

  • Author

    Bradshaw, A.L. ; Schleicher, Karl E.

  • Author_Institution
    Woods Hole Oceanographic Institution, Woods Hole, MA, USA
  • Volume
    5
  • Issue
    1
  • fYear
    1980
  • fDate
    1/1/1980 12:00:00 AM
  • Firstpage
    50
  • Lastpage
    62
  • Abstract
    Measurements of some temperature and pressure dependent relationships of the electrical conductivity of seawater at various salinities were made using four-electrode conductivity cells. At atmospheric pressure the measurements were of the effect of temperature over the range from the freezing point to about 35\\deg C on 1) r_{T} (the ratio of the electrical conductivity of 35^{0}/_{00} seawater at temperature T to that at 15\\deg C) and 2) R_{T} (the ratio of the electrical conductivity of a given seawater at temperature T to that of 35^{0}/_{00} seawater at the same temperature) at various salinities. The results under 1) have been combined with those of Dauphinee [1] and expressed as a fourth degree equation in temperature by Perkin and Lewis [2]. The results under 2) confirm the temperature dependence of the findings of Dauphinee [1] and of Poisson [4] for R_{T} as a function of salinity (weight dilution) at various temperatures. Measurements of the effect of pressure on the electrical conductivity of seawater were made for salinities of 2, 14, 22, and 35^{0}/_{00} over pressure and temperature ranges of 0 to 1000 bars above atmospheric pressure and the freezing point to 30\\deg C, respectively. These results complement those of our earlier work [5] using a two-electrode conductivity cell on 31, 35, and 39\\hbox{ }^{0}/_{00} salinity seawaters over approximately the same pressure and temperature ranges. "Best" least squares polynomial fits in pressure and temperature to the new and to the old observed values of percentage increase in conductivity at 35^{0}/_{00} agree within the equivalent of 0.006^{0}/_{00} salinity at 1000 bars. The accuracy of the new results, which at 35^{0}/_{00} is probably not worse than the equivalent of 0.003^{0}/_{00} salinity at 1000 bars, is superior to that of the earlier ones. Perkin and Lewis [2] have fitted rational functions in P, T, R, and \\sqrt {R} where R is the ratio of the electrical conductivity at P, T, and salinity S to that at 0 bars, 15\\deg C and 35^{0}/_{00} , to the combined old and new edited data. They obtained a standard deviation of 1.3-ppm salinity fo- r their oceanographic fit and a standard deviation of 1.3-ppm salinity for their general fit.
  • Keywords
    Conductivity measurements; Sea measurements; Atmospheric measurements; Bars; Conductivity measurement; Electric variables measurement; Ocean temperature; Poisson equations; Pressure measurement; Temperature dependence; Temperature distribution; Temperature measurement;
  • fLanguage
    English
  • Journal_Title
    Oceanic Engineering, IEEE Journal of
  • Publisher
    ieee
  • ISSN
    0364-9059
  • Type

    jour

  • DOI
    10.1109/JOE.1980.1145449
  • Filename
    1145449