Title :
Tin oxide nanoparticle-modified commercial PtRu catalyst for methanol oxidation
Author :
Wei Wang ; Yong Li ; Hui Wang
Author_Institution :
Key Lab. of Eco-Environ.-Related Polymer Mater., Northwest Normal Univ., Lanzhou, China
Abstract :
The electrocatalytic performance of commercial PtRu/C is significantly enhanced by directly mixing a few SnO2 nanoparticles. The composite catalysts show enhanced CO oxidation, higher activity and better stability than commercial PtRu/C. Among the different ratios of SnO2 nanoparticles (10-40-), the SnO2-PtRu/C (20-) composite catalyst shows the best catalytic activity for methanol oxidation. The effect of temperature on methanol oxidation was also investigated and the apparent activation energy (Ea) value of catalyst was obtained. The results here suggest a simple route to enhance the catalytic efficiency for commercial PtRu/C catalyst.
Keywords :
catalysis; catalysts; mixing; nanocomposites; nanofabrication; nanoparticles; organic compounds; oxidation; platinum alloys; ruthenium alloys; tin compounds; SnO2-PtRu; apparent activation energy; catalytic activity; composite catalysts; electrocatalytic performance; methanol oxidation; mixing; tin oxide nanoparticle-modified commercial PtRu catalyst;
Journal_Title :
Micro & Nano Letters, IET
DOI :
10.1049/mnl.2012.0774