Ceramic processing of YBa/sub 2/Cu/sub 3/O/sub x/ based high-T/sub c/ superconductors

Author

Yan, Man F. ; Ling, Hung C. ; O´Bryan, Henry M. ; Gallagher, Patrick K. ; Rhodes, Warren W.

Author_Institution

AT&T Bell Lab., Murray Hill, NJ, USA

Volume

11

Issue

4

fYear

1988

Firstpage

401

Lastpage

406

Abstract

Ceramic processing of YBa/sub 2/Cu/sub 3/O/sub x/ based superconductors and process-related problems are described. Conditions for calcination, sintering, and microstructural development are important considerations for the superconducting properties. The authors examine different forming techniques to prepare superconducting components with different sizes, shapes, and configurations. They also identify and discuss five problem areas related to: (1) incomplete decomposition of BaCO/sub 3/ precursor; (2) oxidation of YBa/sub 2/Cu/sub 3/O/sub x/ ceramics; (3) sensitivity of the YBa/sub 2/Cu/sub 3/O/sub x/ phase to water; (4) reactivity of the YBa/sub 2/Cu/sub 3/O/sub x/ phase with substrates and co-firing materials; and (5) low critical current density in bulk ceramics of YBa/sub 2/Cu/sub 3/O/sub x/.<>

Keywords

barium compounds; ceramics; critical current density (superconductivity); heat treatment; high-temperature superconductors; oxidation; sintering; yttrium compounds; YBa/sub 2/Cu/sub 3/O/sub x/; calcination; co-firing materials; forming techniques; high-temperature superconductors; incomplete decomposition; low critical current density; microstructural development; oxidation; reactivity; sintering; superconducting properties; water; Calcination; Ceramics; Conducting materials; Powders; Superconducting epitaxial layers; Superconducting filaments and wires; Superconducting films; Superconducting integrated circuits; Superconducting transition temperature; Superconductivity;

fLanguage

English

Journal_Title

Components, Hybrids, and Manufacturing Technology, IEEE Transactions on

Publisher

ieee

ISSN

0148-6411

Type

jour

DOI

10.1109/33.16674

Filename

16674