DocumentCode
1081203
Title
The effect of temperature on the isotopic selectivity and decomposition yield of infrared multiphoton processes
Author
Hackett, Peter ; Gauthier, Michel ; Willis, C. ; Drouin, Michel
Author_Institution
National Research Council of Canada, Ottawa, Ontario, Canada
Volume
16
Issue
2
fYear
1980
fDate
2/1/1980 12:00:00 AM
Firstpage
143
Lastpage
147
Abstract
In this paper we assess the effect of substrate temperature on the isotopic selectivity and dissociation yield of multiphoton dissociation of hexafluoroacetone and trifluoromethyl chloride. In the former molecule, the temperature effects are due to the contribution of vibrational hot bands; in the latter, these effects are overlaid on the kinetic mechanism resulting in a loss of yield of carbon-13 bearing products.
Keywords
Carbon materials/devices; Laser chemistry applications; Thermal factors; Coils; Energy states; Frequency; Kinetic theory; Laser beams; Laser excitation; Mass spectroscopy; Parametric statistics; Parametric study; Temperature sensors;
fLanguage
English
Journal_Title
Quantum Electronics, IEEE Journal of
Publisher
ieee
ISSN
0018-9197
Type
jour
DOI
10.1109/JQE.1980.1070450
Filename
1070450
Link To Document