A detailed theoretical and experimental study of Ag+-Na+ exchange in soda-lime silicate glasses in a molten bath containing a mixture of NaNO
3and Ag+ is presented. With no applied field, concentration profiles

(and therefore, the index profiles for low concentrations) are given by complementary error function. The estimated value for the self-diffusion coefficient

of Ag+ is 0.133 μm
2/min for low concentrations and it monotonically increases with the surface concentration C
0until it saturates at about 0.3 μm
2/min for

MF. However, square root dependence of diffusion depth with time seems to be independent of the C
0. Presence of an external field

causes the effective depth of diffusion to increase. In fact, for large

fields, the profile can accurately be described by

where

where μ is the ionic mobility of Ag
+in glass. We define a new diffusion depth

as the distance from the surface to the

concentration point, and for large fields,

varies linearly with

and

. Experimental results yielded a value of 15.55 μm
2/

min forμ. As before, square root dependence of

with

and the linear variation of

versus C
0for

MF, with

saturating for

MF, were observed in the case of field assisted diffusion. A two-step process, where a surface waveguide formed in the first step with either

equal to zero or some finite value, is modified by performing a second diffusion in pure sodium nitrate to produce a buried, symmetrical fiber-like profile. This process is also studied in detail.