DocumentCode
1120783
Title
Electrodeposited Biaxially Textured Buffer Layers for YBCO Superconductors
Author
Bhattacharya, Raghu ; Phok, Sovannary ; Zhao, Wenjun ; Norman, Andrew
Author_Institution
Nat. Renewable Energy Lab., Golden, CO, USA
Volume
19
Issue
3
fYear
2009
fDate
6/1/2009 12:00:00 AM
Firstpage
3451
Lastpage
3454
Abstract
Non-vacuum electrodeposition (ED) was used to prepare simplified Gd2O3/Gd2Zr2O7 and CeO2/Gd2Zr2O7 buffer layers on a Ni-W substrate. Post-annealing conditions of electrodeposited precursor films were optimized to obtain high-quality biaxially textured buffer layers. The buffer layers were characterized by X-ray diffraction, optical profiling, and transmission electron microscopy (TEM). The effect of the cap layer thickness on the surface morphology and texture of the buffers was also studied. The microstructure of CeO2/Gd2Zr2O7 was analysed and compared to Gd2O3/Gd2Zr2O7. The high-resolution TEM shows biaxially textured crystalline elctrodeposited Gd2O3 and CeO2 cap layers on the electrodeposited Gd2Zr2O7 layers without any defects. YBa2Cu3O7-delta (YBCO) superconductor was deposited by pulsed laser deposition (PLD) on the simplified ED-Gd2O3/Gd2Zr2O7 and ED-CeO2/Gd2Zr2O7 buffers. Transport current density of 3.3 MA/cm2 at 77 K was obtained for PLD YBCO deposited on ED-Gd2O3/Gd2Zr2O7 buffer layers.
Keywords
X-ray diffraction; annealing; barium compounds; buffer layers; cerium compounds; current density; electrodeposition; gadolinium compounds; high-temperature superconductors; nickel alloys; pulsed laser deposition; superconducting thin films; surface morphology; surface texture; transmission electron microscopy; tungsten alloys; yttrium compounds; Ni-W substrate; NiW; TEM; X-ray diffraction; YBCO films; YBa2Cu3O7-delta-CeO2-Gd2Zr2O7-NiW; YBa2Cu3O7-delta-Gd2O3-Gd2Zr2O7-NiW; electrodeposited biaxially textured buffer layers; microstructure; nonvacuum electrodeposition; optical profiling; post-annealing; pulsed laser deposition; surface morphology; surface texture; temperature 77 K; transmission electron microscopy; transport current density; ${rm Gd}_{2}{rm O}_{3}$ ; ${rm CeO}_{2}$ ; ${rm Gd}_{2}{rm Zr}_{2}{rm O}_{7}$ ; Buffer layers; YBCO; electrodeposition; pulsed laser deposition;
fLanguage
English
Journal_Title
Applied Superconductivity, IEEE Transactions on
Publisher
ieee
ISSN
1051-8223
Type
jour
DOI
10.1109/TASC.2009.2019603
Filename
5152914
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