• DocumentCode
    1143858
  • Title

    Threshold voltage (Vth) instability in HfO2 high-κ gate stacks with TiN metal gate: comparison between NH3 and O3 interface treatments

  • Author

    Wang, Xuguang ; Peterson, Jeff ; Majhi, Prashant ; Gardner, Mark I. ; Kwong, Dim-Lee

  • Author_Institution
    Dept. of Electr. & Comput. Eng., Univ. of Texas, Austin, TX, USA
  • Volume
    25
  • Issue
    11
  • fYear
    2004
  • Firstpage
    719
  • Lastpage
    721
  • Abstract
    The impacts of O3 or NH3 interface treatments on the long-term Vth instability in nMOSFET HfO2 high-κ gate stacks with TiN metal gate electrodes are compared. The NH3 interface treatment is found to be beneficial to suppress the Vth shift compared to the O3-treated samples. This is explained by an enhanced valence band electrons injection in O3-treated samples and is experimentally confirmed through a carrier separation measurement. The dynamic stress measurement also indicates that trapped charges are more easily detrapped in NH3-treated samples than O3-treated samples, improving significantly the Vth stability.
  • Keywords
    MOSFET; ammonia; charge injection; electron traps; hafnium compounds; interface phenomena; metal-insulator boundaries; oxygen; titanium compounds; HfO2-TiN; NH3 interface treatment; O3 interface treatment; TiN metal gate; carrier separation measurement; charge trapping; dynamic stress measurement; enhanced valence band electrons; high-k gate stacks; metal gate electrodes; nMOSFET; threshold voltage instability; valence band electrons injection; Electrodes; Electron traps; Hafnium oxide; Lead compounds; MOS devices; MOSFET circuits; Stability; Stress measurement; Threshold voltage; Tin; $V_rm th$ instability; Charge trapping; HfO$_2$; dynamic stress measurement; valance band electrons injection;
  • fLanguage
    English
  • Journal_Title
    Electron Device Letters, IEEE
  • Publisher
    ieee
  • ISSN
    0741-3106
  • Type

    jour

  • DOI
    10.1109/LED.2004.836806
  • Filename
    1347206