• DocumentCode
    1154978
  • Title

    NMR study of Ga and Al substituted hexagonal ferrites with magnetoplumbite structure

  • Author

    Stepankova, Helena ; Englich, Jiri ; Lutgemeier, Hans

  • Author_Institution
    Fac. of Math. & Phys., Charles Univ., Prague, Czechoslovakia
  • Volume
    30
  • Issue
    2
  • fYear
    1994
  • fDate
    3/1/1994 12:00:00 AM
  • Firstpage
    988
  • Lastpage
    990
  • Abstract
    57Fe NMR spectra and relaxation rates in lead hexaferrite single crystals PbFe12O19, PbFe12-xGaxO19, (x=0.42, 1.2) and PbFe 12-xAlxO19, (x=0.21) have been measured at 4.2 K using spin echo technique. Besides the main lines corresponding to the nonequivalent positions of Fe3+ ions in the magnetoplumbite structure, the satellite lines caused by substitution in the vicinity of resonating nuclei have been observed. The dependence of the NMR spectrum on the external magnetic field has been used to separate the overlapped satellites from different iron sites. The most distant satellites have been assigned to the resonance of iron nuclei at 4f1 site with substitution at 12 k and 2a sites in their vicinity. A strong preference of 2a site for Al substitution has been found
  • Keywords
    ferrites; lead compounds; nuclear magnetic resonance; nuclear spin-lattice relaxation; spin echo (NMR); 4.2 K; 57Fe; Al substitution; Fe3+ ions; Ga substitution; NMR; Pb(FeAl)12O19; Pb(FeGa)12O19; PbFe12-xAlxO19; PbFe12-xGaxO19; PbFe12O19; external magnetic field; hexagonal ferrites; magnetoplumbite structure; relaxation rates; satellite lines; single crystals; spin echo technique; Crystals; Ferrites; Frequency; Iron; Lead; Magnetic domains; Magnetic separation; Nuclear magnetic resonance; Pulse measurements; Satellites;
  • fLanguage
    English
  • Journal_Title
    Magnetics, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0018-9464
  • Type

    jour

  • DOI
    10.1109/20.312467
  • Filename
    312467