DocumentCode
1154978
Title
NMR study of Ga and Al substituted hexagonal ferrites with magnetoplumbite structure
Author
Stepankova, Helena ; Englich, Jiri ; Lutgemeier, Hans
Author_Institution
Fac. of Math. & Phys., Charles Univ., Prague, Czechoslovakia
Volume
30
Issue
2
fYear
1994
fDate
3/1/1994 12:00:00 AM
Firstpage
988
Lastpage
990
Abstract
57Fe NMR spectra and relaxation rates in lead hexaferrite single crystals PbFe12O19, PbFe12-xGaxO19, (x=0.42, 1.2) and PbFe 12-xAlxO19, (x=0.21) have been measured at 4.2 K using spin echo technique. Besides the main lines corresponding to the nonequivalent positions of Fe3+ ions in the magnetoplumbite structure, the satellite lines caused by substitution in the vicinity of resonating nuclei have been observed. The dependence of the NMR spectrum on the external magnetic field has been used to separate the overlapped satellites from different iron sites. The most distant satellites have been assigned to the resonance of iron nuclei at 4f1 site with substitution at 12 k and 2a sites in their vicinity. A strong preference of 2a site for Al substitution has been found
Keywords
ferrites; lead compounds; nuclear magnetic resonance; nuclear spin-lattice relaxation; spin echo (NMR); 4.2 K; 57Fe; Al substitution; Fe3+ ions; Ga substitution; NMR; Pb(FeAl)12O19; Pb(FeGa)12O19; PbFe12-xAlxO19; PbFe12-xGaxO19; PbFe12O19; external magnetic field; hexagonal ferrites; magnetoplumbite structure; relaxation rates; satellite lines; single crystals; spin echo technique; Crystals; Ferrites; Frequency; Iron; Lead; Magnetic domains; Magnetic separation; Nuclear magnetic resonance; Pulse measurements; Satellites;
fLanguage
English
Journal_Title
Magnetics, IEEE Transactions on
Publisher
ieee
ISSN
0018-9464
Type
jour
DOI
10.1109/20.312467
Filename
312467
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