Title :
Kohlrausch relaxations: new aspects about the everlasting story
Author_Institution :
Inst. of Electr. Eng. Phys., Saarlandes Univ., Saarbrucken, Germany
Abstract :
For transient, time dependent polarization processes stretched exponential functions and power laws referred to as Kohlrausch relaxations are often observed in disordered dielectrics. These relaxations can be distributed in time or frequency over more than 12 decades. Among the various existing models for an interpretation two of them based on similar mathematics but different physical grounds are repeated. In these models charges, either electrons or protons, hop between adjacent sites. The distances between the sites are distributed resulting in a distribution of relaxation times. Then two new models which emerged in the last years are discussed. (I) It is shown that the dipolar interaction between dipoles of the same kind, i.e. without a distribution of any property, can result in Kohlrausch relaxations. (II) In solid electrolytic capacitors charges can be attracted by their images in the electrode. After application of an external voltage this charge attraction leads to an external current with a power law time dependence.
Keywords :
Monte Carlo methods; dielectric polarisation; dielectric relaxation; electrodes; electrolytic capacitors; time-frequency analysis; Kohlrausch relaxation; Monte Carlo methods; dipolar interaction; disordered dielectrics; distribution function; electrode; insulator; power laws; solid electrolytic capacitor; stretched exponential function; time dependent polarization process; transient; Capacitors; Dielectrics; Electrodes; Electrons; Frequency; Mathematical model; Mathematics; Polarization; Protons; Solid modeling;
Journal_Title :
Dielectrics and Electrical Insulation, IEEE Transactions on
DOI :
10.1109/TDEI.2005.1511096