Effects of manufacturing technology on electrical breakdown and morphology of thin films of low density polyethylene blended with polypropylene copolymer

Extruded films prepared from blends of low-density polyethylene (LDPE) and random copolymer of ethylene and propylene (EP) with the T-die method were studied with respect to electrical properties and morphology. Comparisons with data on blown films are made. These blends are of interest as improved LDPE for making XLPE for insulated power cable. In the high temperature region (90°C), a specimen with a slightly higher EP content had higher impulse breakdown strength than that with a lower EP content, but no improvement of DC breakdown strength by blending could be found. The improvement of impulse breakdown strength (90°C) is explained in terms of morphological changes by blending such as the orientation of chains in a film and the size of spherulites on the assumption of the thermal breakdown. In comparison, a T-die film had higher impulse breakdown strength than that of a blown film for the same composition. The impulse breakdown strength also increased with the use of the higher density LDPE. In the current versus electric field characteristics at 30°C, the blend polymer with EP content of 5-10% showed a transition from LDPE behavior at low field region to EP behavior at high field region. However, no appreciable difference in current behavior among the specimens was observed at 90°C, which suggests an incompatibility between the two materials that exists at 30°C but not at 90°C.