DocumentCode
1280628
Title
Synthesis of gold nanostructures using Langmuir monolayers of ionic liquid-type Gemini imidazolium surfactants
Author
Qing-Yu Ma ; Rui-Fang Guan ; Guo-Zhong Li
Author_Institution
Sch. of Mater. Sci. & Eng., Univ. of Jinan, Jinan, China
Volume
6
Issue
6
fYear
2011
fDate
6/1/2011 12:00:00 AM
Firstpage
454
Lastpage
458
Abstract
Gold nanostructures are successfully synthesised under Langmuir monolayers of ionic liquid-type Gemini imidazolium surfactants [Cnim-4-Cnim][Br2] (n=10, 16) through interfacial reduction of AuCl4- by formaldehyde gas. The Au nanostructures are characterised using transmission electron microscopy and UV-vis spectroscopy. It is found that the concentration of HAuCl4 aqueous solution, the surface pressure and the length of the hydrophobic chains of the surfactants strongly influence the formation of Au nanostructures. A potential mechanism of such diverse morphologies is also discussed.
Keywords
gold; hydrophobicity; monolayers; nanofabrication; nanostructured materials; reduction (chemical); surfactants; transmission electron microscopy; ultraviolet spectra; visible spectra; Au; Langmuir monolayers; UV-vis spectra; formaldehyde gas; interfacial reduction; ionic liquid-type Gemini imidazolium surfactants; nanostructured materials; transmission electron microscopy;
fLanguage
English
Journal_Title
Micro & Nano Letters, IET
Publisher
iet
ISSN
1750-0443
Type
jour
DOI
10.1049/mnl.2011.0165
Filename
5960472
Link To Document