• DocumentCode
    1280628
  • Title

    Synthesis of gold nanostructures using Langmuir monolayers of ionic liquid-type Gemini imidazolium surfactants

  • Author

    Qing-Yu Ma ; Rui-Fang Guan ; Guo-Zhong Li

  • Author_Institution
    Sch. of Mater. Sci. & Eng., Univ. of Jinan, Jinan, China
  • Volume
    6
  • Issue
    6
  • fYear
    2011
  • fDate
    6/1/2011 12:00:00 AM
  • Firstpage
    454
  • Lastpage
    458
  • Abstract
    Gold nanostructures are successfully synthesised under Langmuir monolayers of ionic liquid-type Gemini imidazolium surfactants [Cnim-4-Cnim][Br2] (n=10, 16) through interfacial reduction of AuCl4- by formaldehyde gas. The Au nanostructures are characterised using transmission electron microscopy and UV-vis spectroscopy. It is found that the concentration of HAuCl4 aqueous solution, the surface pressure and the length of the hydrophobic chains of the surfactants strongly influence the formation of Au nanostructures. A potential mechanism of such diverse morphologies is also discussed.
  • Keywords
    gold; hydrophobicity; monolayers; nanofabrication; nanostructured materials; reduction (chemical); surfactants; transmission electron microscopy; ultraviolet spectra; visible spectra; Au; Langmuir monolayers; UV-vis spectra; formaldehyde gas; interfacial reduction; ionic liquid-type Gemini imidazolium surfactants; nanostructured materials; transmission electron microscopy;
  • fLanguage
    English
  • Journal_Title
    Micro & Nano Letters, IET
  • Publisher
    iet
  • ISSN
    1750-0443
  • Type

    jour

  • DOI
    10.1049/mnl.2011.0165
  • Filename
    5960472