• DocumentCode
    1316997
  • Title

    Synthesis and chemical properties of Y2O2S: Eu3+ nanostructures using composite-hydroxide-mediated method

  • Author

    Thirumalai, J. ; Chandramohan, R. ; Valanarasu, S. ; Vijayan, T.A. ; Ezhilvizhian, S.

  • Author_Institution
    Dept. of Phys., B.S. Abdur Rahman Univ., Chennai, India
  • Volume
    6
  • Issue
    8
  • fYear
    2011
  • fDate
    8/1/2011 12:00:00 AM
  • Firstpage
    614
  • Lastpage
    618
  • Abstract
    One-dimensional (1D) Y2O2S:Eu3+ nanostructures were successfully synthesised using a composite-hydroxide-mediated method based on the use of molten composite hydroxides as solvent in chemical reactions at ~200°C. The important role in the initial nucleation stage of growing oriented Y2O2S:Eu3+ nanostructures by controlling the reaction parameters such as the molar ratio between the inorganic precursor and hydroxyl ions, temperature and reaction time are discussed. A reasonable control of the size and morphology are achieved. The advantages of low synthesis temperature, low pressure and low cost in the synthesis of functional nanostructures are presented. The morphology and the phase composition of the prepared nanostructures were characterised by scanning electron microscopy, transmission electron microscopy, X-ray diffraction and energy disperse spectroscopy. The room-temperature photoluminescence spectra indicate its potential applications in light-emission devices.
  • Keywords
    X-ray chemical analysis; X-ray diffraction; chemical reactions; europium; nanofabrication; nanorods; nucleation; photoluminescence; scanning electron microscopy; transmission electron microscopy; yttrium compounds; X-ray diffraction; Y2O2S:Eu; chemical properties; chemical reactions; energy disperse X-ray spectroscopy; hydroxyl ions; light emission devices; low pressure synthesis; low temperature synthesis; molten composite hydroxide mediated method; morphology; nanobelts; nanorods; nanostructured materials; nucleation; phase composition; photoluminescence; scanning electron microscopy; temperature 293 K to 298 K; transmission electron microscopy;
  • fLanguage
    English
  • Journal_Title
    Micro & Nano Letters, IET
  • Publisher
    iet
  • ISSN
    1750-0443
  • Type

    jour

  • DOI
    10.1049/mnl.2011.0252
  • Filename
    6012998