Title :
Coercivity Enhancement in
-Based Nanocrystalline Materials Due to Mo Addition
Author :
Zhang, Wenyong ; Valloppilly, Shah R. ; Li, Xingzhong ; Skomski, Ralph ; Shield, Jeffrey E. ; Sellmyer, David J.
Author_Institution :
Dept. of Phys. & Astron., Univ. of Nebraska, Lincoln, NE, USA
Abstract :
The Mo-content dependence of structure and magnetic properties of Zr16Co78-xMoxSi3B3 ( x=0, 2, 3, 4, 5) nanocrystalline materials has been studied. The samples consist of hard-magnetic Zr2Co11 and soft-magnetic Co phases. The substitution of Mo for Co restrains the formation of Co, raises the content of Zr2Co11, and increases the mean grain size of Zr2Co11. Therefore, the coercive force of the sample increases with x. A coercive force of 7.9 kOe, which is a highest value reported among Zr-Co alloys, was achieved for x=5. The anisotropy field of Zr2Co11 remains almost unchanged with increasing Mo content.
Keywords :
boron alloys; cobalt alloys; coercive force; crystal structure; grain size; magnetic anisotropy; magnetic structure; melt spinning; molybdenum alloys; nanofabrication; nanomagnetics; nanostructured materials; permanent magnets; silicon alloys; soft magnetic materials; zirconium alloys; Mo addition; Zr16Co78-xMoxSi3B3; anisotropy ήeld; coercive force; coercivity enhancement; grain size; hard-magnetic phases; magnetic properties; melt spinning; nanocrystalline materials; soft-magnetic phases; structural properties; Anisotropic magnetoresistance; Coercive force; Magnetic hysteresis; Materials; Perpendicular magnetic anisotropy; Saturation magnetization; Coercive force; intermetallic; magnetic property; nanomaterials;
Journal_Title :
Magnetics, IEEE Transactions on
DOI :
10.1109/TMAG.2012.2198453