Title :
Product characterization and kinetic study of co-pyrolysis of waste jute sacks and sesame oil cake
Author :
Poddar, Sunrita ; Biswas, Rubel ; Chowdhury, Rajdeep ; De, Suvranu
Author_Institution :
Dept. of Chem. Eng., Jadavpur Univ., Kolkata, India
Abstract :
The co-pyrolysis of sesame oil cake and the waste jute sacks has been conducted in a long tubular type semi-batch reactor in the temperature range of 573 to 1173K in N2 atmosphere. A reaction scheme has been proposed where two parallel reactions occur simultaneously to produce volatiles and char. Kinetic parameters, namely, rate constants, frequency factors, activation energies have been determined through nonlinear regression analysis. Effects of co-pyrolysis temperature have been observed on product yields. The pH value of the oil confirmed that the oil is acidic in nature. The functional groups of the pyro-oil have been analyzed by Fourier Transform Infrared (FTIR) spectroscopy to identify the basic functional groups. The energy yield of the pyro-oil has been calculated.
Keywords :
Fourier transform spectra; bioenergy conversion; biofuel; bioreactors; industrial waste; infrared spectra; oils; pyrolysis; reaction rate constants; regression analysis; FTIR; Fourier transform infrared spectroscopy; N2 atmosphere; activation energy; co-pyrolysis temperature effects; energy technology; energy yield; frequency factors; kinetic parameters; kinetic study; long tubular type semibatch reactor; nonlinear regression analysis; pH value; parallel reactions; product characterization; product yields; pyro-oil; rate constants; sesame oil cake co-pyrolysis; temperature 573 K to 1173 K; waste jute sack co-pyrolysis; Biological system modeling; Carbon; Correlation; Integrated circuits; Spectroscopy; FTIR; co-pyrolysis kinetic; co-pyrolysis product yield; energy yield; jute; pH value; sesame oil cake;
Conference_Titel :
Power and Energy Systems Conference: Towards Sustainable Energy, 2014
Conference_Location :
Bangalore
Print_ISBN :
978-1-4799-3420-1
DOI :
10.1109/PESTSE.2014.6805290