Title :
Plasma-Driven Catalysis Process for Toluene Abatement: Effect of Water Vapor
Author :
Huang, Haibao ; Ye, Daiqi ; Leung, Dennis Y C
Author_Institution :
Coll. of Environ. Sci. & Eng., South China Univ. of Technol., Guangzhou, China
Abstract :
Plasma-driven catalysis (PDC) was used to remove toluene in air. Water vapor is a critical operating parameter in this process. Its effect on toluene removal efficiency, carbon balance, CO2 selectivity, and outlet O3 concentration was systematically investigated. Results showed that water vapor imposed negative effect on toluene decomposition since it depressed the formation and catalytic decomposition of O3. Water vapor deposited on the catalyst would cover the catalytic active sites, resulting in the deactivation of the catalyst. There was an optimum water vapor content for the highest carbon balance and CO2 selectivity. The present paper sheds some insight into the effect of water vapor and provides a valuable basis for the application of the PDC technology.
Keywords :
atmospheric chemistry; atmospheric humidity; carbon compounds; catalysis; catalysts; organic compounds; ozone; plasma applications; plasma chemistry; CO2; CO2 selectivity; O3; PDC technology; carbon balance; catalyst deactivation; catalytic active site; outlet O3 concentration; plasma-driven catalysis process; toluene abatement; toluene decomposition; toluene removal efficiency; water vapor effect; Aluminum oxide; Carbon; Carbon dioxide; Inductors; Partial discharges; Plasmas; Water pollution; Ozone; plasma-driven catalysis (PDC); toluene; water vapor content;
Journal_Title :
Plasma Science, IEEE Transactions on
DOI :
10.1109/TPS.2010.2086498