The Effect of Low Frequency External Field Disturbance on the SQUID Based Ultra-Low Field NMR Measurements

We have carried out NMR experiments in the microtesla range using a high-T_c DC-SQUID sensor. The measurements were carried out in a simple magnetically shielded room. Resonance spectra of ¹H nuclei from tap water and other substance samples were obtained in the field range 7-70 μT. The effect of frequency, strength, direction and phase of a low frequency external disturbance field on the NMR spectra was investigated. A sinusoidal field was applied along or perpendicular to the measurement field to simulate the external disturbance. The results were compared with the numerical calculations based on the Bloch equation and good agreement was obtained. In all cases, the field disturbance less than a few Hz are proved to influence the NMR spectra more severely, suppressing the resonance peak and driving it into split bands. On the other hand, the influence of the disturbance field at the frequency range around 50 Hz on the resonance peak position and profile is small, even though some additional small peaks appear in the spectra due to frequency mixing. The effect is more significant when the disturbance field is along the direction of the measurement field. The phase difference between the disturbance field and the free-induction-decay signal could change the NMR peak position and profile drastically.