Title :
A new class of Sm-TM magnets for operating temperatures up to 550°C
Author :
Walmer, Marlin S. ; Chen, Christina H. ; Walmer, Michael H.
Author_Institution :
Electron Energy Corp., Landisville, PA, USA
fDate :
9/1/2000 12:00:00 AM
Abstract :
A breakthrough has been made for magnets to be used at high temperatures. A new class of Sm(CowFevCux Zry)z type magnets with linear demagnetization curves up to 550°C has been developed. A new symbol, TM, is introduced, which is defined as the maximum temperature at which the induction demagnetization curve of a magnet is a straight line. A magnet in this class can be made with its own unique TM. There is a direct relationship between the optimum Co content and TM. An equation has been established to relate the Co content and the TM. Using the equation, magnets can be provided with the best combination of highest (BH)max and a linear demagnetization curve for any application with a specified operating temperature. These magnets have high resistance to thermal demagnetization because of their low temperature coefficients of i Hc which result in a higher iHc at high temperature. Thermal stability of these magnets at 300-550°C has been studied, showing that the loss due to metallurgical changes is <2% for new magnets at 550°C for 360 hr. Experiment confirms that coated magnets can be expected to have considerable life expectancy and relatively low magnetic losses at the intended TM. Experiment also shows that, at high temperatures, the magnetic pinning strength in the magnets increases as the TM increases. TEM microstructures for some magnets have been studied. Magnets with higher TM have smaller cell sizes and larger volume of cell boundaries than conventional 2:17 magnets. It is believed that the large volume of cell boundaries plays a role in the high resistance to thermal demagnetization
Keywords :
cobalt alloys; copper alloys; crystal microstructure; demagnetisation; electromagnetic induction; ferromagnetic materials; iron alloys; magnetic leakage; permanent magnets; samarium alloys; thermal stability; transmission electron microscopy; zirconium alloys; 300 to 550 degC; Sm(CowFevCuxZry) z type magnets; Sm-TM magnets; SmCoFeCuZr; TEM microstructures; cell boundaries; coated magnets; high temperatures; induction demagnetization curve; life expectancy; linear demagnetization curves; low temperature coefficients; magnetic losses; magnetic pinning strength; maximum temperature; metallurgical changes; operating temperature; operating temperatures; optimum Co content; thermal demagnetization; thermal stability; Demagnetization; Equations; Iron; Magnetic losses; Magnets; Microstructure; Temperature; Thermal resistance; Thermal stability; Zirconium;
Journal_Title :
Magnetics, IEEE Transactions on