DocumentCode
1450433
Title
Magnetic Investigation of CoFe
O
Nanoparticles Supported in Biocompatible Polymeric Micr
Author
Coaquira, J.A.H. ; Vaccari, C.B. ; Tedesco, A.C. ; Morais, P.C.
Author_Institution
Inst. de Fis., Nucleo de Fis. Aplic., Univ. de Brasilia, Brasilia, Brazil
Volume
45
Issue
10
fYear
2009
Firstpage
4059
Lastpage
4062
Abstract
Magnetic investigation of spinel ferrite nanoparticles dispersed in biocompatible polymeric microspheres is reported in this study. X-ray diffraction data analysis confirms the presence of nanosized CoFe2O4 particles (mean size of ~8 nm). This finding is corroborated by transmission electron microscopy micrographs. Magnetization isotherms suggest a spin disorder likely occurring at the nanoparticle´s surface. The saturation magnetization value is used to estimate particle concentration of 1.6times1018 cm-3 dispersed in the polymeric template. A T1/2 dependence of the coercive field is determined in the low-temperature region (T < 30 K). The model of non-interacting mono-domains is used to estimate an effective magnetic anisotropy of Keff = 0.6times105 J/m3. The Keff value we found is lower than the value reported for spherically-shaped CoFe2O4 nanoparticles, though consistent with the low coercive field observed in the investigated sample.
Keywords
X-ray diffraction; cobalt compounds; coercive force; ferrites; magnetic hysteresis; nanoparticles; transmission electron microscopy; CoFe2O4; X-ray diffraction data analysis; biocompatible polymeric microsphere; coercive field; effective magnetic anisotropy; hysteresis loops; magnetization isotherms; noninteracting mono-domains; particle concentration; saturation magnetization; spinel ferrite nanoparticles; transmission electron microscopy; Magnetic coercive field; magnetic fluid; magnetization isotherm; polymer dispersed CoFe$_{2}$ O $_{4}$ nanoparticles; thermal blocking process;
fLanguage
English
Journal_Title
Magnetics, IEEE Transactions on
Publisher
ieee
ISSN
0018-9464
Type
jour
DOI
10.1109/TMAG.2009.2026291
Filename
5257196
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