• DocumentCode
    1450433
  • Title

    Magnetic Investigation of CoFe _{2} O _{4} Nanoparticles Supported in Biocompatible Polymeric Micr

  • Author

    Coaquira, J.A.H. ; Vaccari, C.B. ; Tedesco, A.C. ; Morais, P.C.

  • Author_Institution
    Inst. de Fis., Nucleo de Fis. Aplic., Univ. de Brasilia, Brasilia, Brazil
  • Volume
    45
  • Issue
    10
  • fYear
    2009
  • Firstpage
    4059
  • Lastpage
    4062
  • Abstract
    Magnetic investigation of spinel ferrite nanoparticles dispersed in biocompatible polymeric microspheres is reported in this study. X-ray diffraction data analysis confirms the presence of nanosized CoFe2O4 particles (mean size of ~8 nm). This finding is corroborated by transmission electron microscopy micrographs. Magnetization isotherms suggest a spin disorder likely occurring at the nanoparticle´s surface. The saturation magnetization value is used to estimate particle concentration of 1.6times1018 cm-3 dispersed in the polymeric template. A T1/2 dependence of the coercive field is determined in the low-temperature region (T < 30 K). The model of non-interacting mono-domains is used to estimate an effective magnetic anisotropy of Keff = 0.6times105 J/m3. The Keff value we found is lower than the value reported for spherically-shaped CoFe2O4 nanoparticles, though consistent with the low coercive field observed in the investigated sample.
  • Keywords
    X-ray diffraction; cobalt compounds; coercive force; ferrites; magnetic hysteresis; nanoparticles; transmission electron microscopy; CoFe2O4; X-ray diffraction data analysis; biocompatible polymeric microsphere; coercive field; effective magnetic anisotropy; hysteresis loops; magnetization isotherms; noninteracting mono-domains; particle concentration; saturation magnetization; spinel ferrite nanoparticles; transmission electron microscopy; Magnetic coercive field; magnetic fluid; magnetization isotherm; polymer dispersed CoFe$_{2}$O $_{4}$ nanoparticles; thermal blocking process;
  • fLanguage
    English
  • Journal_Title
    Magnetics, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0018-9464
  • Type

    jour

  • DOI
    10.1109/TMAG.2009.2026291
  • Filename
    5257196