Title :
Structure and magnetism in the systems Zr3(Rh1-x Rux)4 and Zr3(Rh1-yPd y)4
Author :
Bennett, L.H. ; Waterstrat, R.M. ; Swartzendruber, L.J. ; Watson, R.E.
Author_Institution :
Inst. for Magnetics Res., George Washington Univ., Ashburn, VA, USA
fDate :
9/1/2000 12:00:00 AM
Abstract :
The Zr3(Rh(1-y)Pdy)4 system in the Pu3Pd4 structure, reported on previously, is further investigated here. It exhibits an incommensurate density wave for 0.04 ⩽y⩽ 0.06, accompanied by strongly varying paramagnetism. It displays weak ferromagnetism at one composition and weak superconductivity at an other. Changes in cooperative behavior with such small changes in composition are unique for a metallic system. The present results indicate that there is a charge density wave of constant wave vector direction and varying lattice displacements in this composition range, with microcracks developing for y=0.04
Keywords :
charge density waves; crystal structure; ferromagnetic materials; magnetisation; palladium alloys; rhodium alloys; ruthenium alloys; zirconium alloys; Zr3(Rh1-xRux)4; Zr3(Rh1-yPdy)4; Zr3(RhPd)4; Zr3(RhRu)4; charge density wave; crystal structure; ferromagnetism; incommensurate density wave; magnetization; microcrack; paramagnetism; superconductivity; Annealing; Magnetic materials; Microstructure; NIST; Neutrons; Powders; Scanning electron microscopy; Superconducting magnets; X-ray diffraction; Zirconium;
Journal_Title :
Magnetics, IEEE Transactions on