Title :
A Novel Process to Produce Amorphous Nanosized Boron Useful for
Synthesis
Author :
Vignolo, M. ; Romano, G. ; Martinelli, A. ; Bernini, C. ; Siri, A.S.
Author_Institution :
SPIN, Genoa, Italy
Abstract :
In this paper, we report a new synthesis route to produce boron powders characterized as being amorphous and having very fine particle size. This route has been developed to improve the performances of superconducting MgB2 powders, which can be directly synthesized from this nanostructured boron precursor by following the ex-situ or the in-situ PIT method during manufacturing of tapes, wires, and cables. All the procedure steps are explained, and the chemical-physical characterization of the boron powder, using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy techniques, is reported. Furthermore, a comparison with commercial boron is given. Preliminary results of the magnetic and electrical characterization, such as critical temperature TC and transport critical current density JC t, for the MgB2 tape are reported and compared with those for the tape prepared with commercial boron.
Keywords :
X-ray diffraction; amorphous state; critical current density (superconductivity); magnesium compounds; nanofabrication; nanoparticles; particle size; powder technology; powders; scanning electron microscopy; superconducting cables; superconducting tapes; superconducting transition temperature; transmission electron microscopy; MgB2; PIT method; SEM technique; TEM technique; X-ray diffraction; XRD technique; amorphous nanosized boron; boron powders; cable manufacturing; chemical-physical characterization; critical temperature; electrical characterization; magnetic characterization; nanostructured boron precursor; particle size; procedure steps; scanning electron microscopy; superconducting powder performances; synthesis route; tape manufacturing; transmission electron microscopy; transport critical current density; wire manufacturing; Boron; Chemical elements; Heat treatment; Nickel; Powders; Solids; X-ray scattering; Boron synthesis; criticalcurrent density; ex-situ MgB2 tape; powder processing;
Journal_Title :
Applied Superconductivity, IEEE Transactions on
DOI :
10.1109/TASC.2012.2190510