DocumentCode
1509119
Title
Coupling model explanation of salient dynamic properties of glass-forming substances
Author
Ngai, K.L.
Author_Institution
Naval Res. Lab., Washington, DC, USA
Volume
8
Issue
3
fYear
2001
fDate
6/1/2001 12:00:00 AM
Firstpage
329
Lastpage
344
Abstract
Most of the important and general dynamic properties of structural glass-forming substances have been classified into twelve different categories in a recent review. Within the same property in each category, by examining a large number of glass-formers, a pattern of variation is found which correlates with the departure of the structural relaxation of the glass-former from exponential decay or the quantity 1-β, where β is the fractional exponent in the Kohlrausch expression exp[-(t/τ)β], that well describes the time dependence of the structural at relaxation. The correlation of the patterns or trends with 1-β suggests that the salient dynamic properties, or phenomenology, of glass-forming substances, all are governed by the non-exponential nature of the structural relaxation, i.e. the quantity 1-β. Therefore, a theory or model capable of relating the structural relaxation time τ to 1-β has the potential of explaining most, if not all, of the salient dynamic properties of glass-forming substances. The coupling model of the author has this relation. In this accompanying paper we show the coupling model can either explain or interpret all these properties
Keywords
glass structure; glass transition; relaxation; Kohlrausch expression; coupling model; glass-forming substances; salient dynamic properties; structural relaxation; Chemicals; Frequency; Laboratories; Liquids; Predictive models;
fLanguage
English
Journal_Title
Dielectrics and Electrical Insulation, IEEE Transactions on
Publisher
ieee
ISSN
1070-9878
Type
jour
DOI
10.1109/94.933340
Filename
933340
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