• DocumentCode
    1509119
  • Title

    Coupling model explanation of salient dynamic properties of glass-forming substances

  • Author

    Ngai, K.L.

  • Author_Institution
    Naval Res. Lab., Washington, DC, USA
  • Volume
    8
  • Issue
    3
  • fYear
    2001
  • fDate
    6/1/2001 12:00:00 AM
  • Firstpage
    329
  • Lastpage
    344
  • Abstract
    Most of the important and general dynamic properties of structural glass-forming substances have been classified into twelve different categories in a recent review. Within the same property in each category, by examining a large number of glass-formers, a pattern of variation is found which correlates with the departure of the structural relaxation of the glass-former from exponential decay or the quantity 1-β, where β is the fractional exponent in the Kohlrausch expression exp[-(t/τ)β], that well describes the time dependence of the structural at relaxation. The correlation of the patterns or trends with 1-β suggests that the salient dynamic properties, or phenomenology, of glass-forming substances, all are governed by the non-exponential nature of the structural relaxation, i.e. the quantity 1-β. Therefore, a theory or model capable of relating the structural relaxation time τ to 1-β has the potential of explaining most, if not all, of the salient dynamic properties of glass-forming substances. The coupling model of the author has this relation. In this accompanying paper we show the coupling model can either explain or interpret all these properties
  • Keywords
    glass structure; glass transition; relaxation; Kohlrausch expression; coupling model; glass-forming substances; salient dynamic properties; structural relaxation; Chemicals; Frequency; Laboratories; Liquids; Predictive models;
  • fLanguage
    English
  • Journal_Title
    Dielectrics and Electrical Insulation, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    1070-9878
  • Type

    jour

  • DOI
    10.1109/94.933340
  • Filename
    933340