• DocumentCode
    1509213
  • Title

    Synthesis, structure and conduction of a novel radical cation salt, (ET)5Dy(NCS)6NO3.C2H5 OH

  • Author

    Kushch, N.D. ; Nazheva, O.N. ; Gritsenko, V.V. ; Buravov, L.I. ; Dyachenko, O.A. ; Van, K.V.

  • Author_Institution
    Inst. of Problems of Chem. Phys., Acad. of Sci., Chernogolovka, Russia
  • Volume
    8
  • Issue
    3
  • fYear
    2001
  • fDate
    6/1/2001 12:00:00 AM
  • Firstpage
    429
  • Lastpage
    431
  • Abstract
    A new radical cation salt (ET)5Dy(NCS)6No 3.C2H5OH based on a complex dysprosium anion was prepared by electrochemical oxidation of bis (ethylenedithio)tetrathiafulvalene (ET) in a chlorobenzene-ethanol solution. Its crystal structure and conducting properties were studied. The salt has a layered crystal structure with a new type of packing of the radical cation layer, which is called ω type. Its electrical properties show that this salt is a semiconductor
  • Keywords
    crystal structure; electrical conductivity; electrochemistry; materials preparation; organic semiconductors; oxidation; semiconductor growth; ω type packing; (ET)5Dy(NCS)6NO3.C2H 5OH; bis (ethylenedithio)tetrathiafulvalene; chlorobenzene-ethanol solution; conduction; crystal structure; dysprosium anion; electrical properties; electrochemical oxidation; layered crystal structure; radical cation salt; semiconductor; structure; synthesis; Chemicals; Conductors; Crystals; Electrodes; Ethanol; Filling; Oxidation; Physics; Platinum; Superconductivity;
  • fLanguage
    English
  • Journal_Title
    Dielectrics and Electrical Insulation, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    1070-9878
  • Type

    jour

  • DOI
    10.1109/94.933360
  • Filename
    933360
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=1509213