Title :
Chemical Oxide Interfacial Layer for the High-
-Last/Gate-Last Integration Scheme
Author :
Chen, Ying-Tsung ; Fu, Ssu-I ; Chiang, Wen-Tai ; Lin, Chien-Ting ; Tsai, Shih-Hung ; Wang, Shao-Wei ; Chang, Shoou-Jinn
Author_Institution :
Dept. of Electr. Eng., Nat. Cheng Kung Univ., Tainan, Taiwan
fDate :
7/1/2012 12:00:00 AM
Abstract :
The authors propose a high-k-last with gate-last integration scheme with a chemical oxide interfacial layer (IL). It was found that chemical oxide IL could form Hf-silicate at the high-k/IL interface so as to provide us a larger effective k value and a smaller equivalent oxide thickness (EOT). It was also found that the larger leakage current density for the samples with chemical oxide IL could be effectively suppressed by postdeposition annealing (PDA). Furthermore, it was found that PDA-induced larger EOT could be reduced by optimizing the metal gate stack.
Keywords :
annealing; atomic layer deposition; current density; hafnium compounds; high-k dielectric thin films; leakage currents; silicon compounds; surface chemistry; EOT; Hf-SiO4; PDA; atomic layer deposition; chemical oxide IL; chemical oxide interfacial layer; equivalent oxide thickness; high-k-IL interface; high-k-last-gate-last integration scheme; leakage current density; metal gate stack optimization; postdeposition annealing; Chemicals; Current measurement; High K dielectric materials; Leakage current; Logic gates; Metals; Silicon; Equivalent oxide thickness (EOT); Si–O–Hf; high-$k$ ; postdeposition annealing (PDA); work function metal;
Journal_Title :
Electron Device Letters, IEEE
DOI :
10.1109/LED.2012.2195292