In this paper, we introduce our work on material characteristics, device characteristics, and performance considerations for armchair graphene nanoribbons (AGNRs) and AGNR field-effect transistors (AGNRFETs). First, we show that the effective-mass-versus-band-gap relationship can be described by a group of lines. By simply tight-binding a model considering only the first-nearest neighbor interaction, the effective-mass-versus-band-gap relationship for AGNRs can be described by two lines crossing zero, which is further separated into three lines if considering third-nearest neighbor interaction and edge bond relaxation. Second, we show the quantum transport calculations for AGNRFETs. We found that a smaller/larger off-state leakage current in the
–
curve may be always accompanied with a smaller/larger on-current in the
–
curve, which is then explained by full complex band structure characteristics. Finally, we show that, to achieve a certain on-current–off-current ratio for 10-nm AGNRFETs, smooth edges are needed for AGNRs with a width of about 3 nm at most.