Aging of Kraft paper by acid catalyzed hydrolysis

Hydrolysis of transformer insulating Kraft paper is experimentally investigated. Paper moisture content was varied and five different acids representative of what may be found in an aging transformer - were added to the oil. The low molecular weight acids were to a large degree absorbed by the paper, contrary to the high molecular acids that remained in the oil. The three low molecular acids accelerated the aging of the paper, and a clear synergy between these acids and water content was found. The high molecular acids did not influence the paper aging significantly. The results support a theory explaining the hydrolysis as governed by acid catalysis. Examples from measurements on real transformers are shown. It is concluded that low molecular acids constitute an important aging factor for transformer windings and should be included in diagnostic schemes, and when estimating the pay-back from maintenance actions.