Title :
Synthesis and ferromagnetism of Mn-doped nanocrystalline ZnO thin films
Author :
Zhao, X. ; Zhang, Peng ; Li, T. ; Harako, S. ; Okamoto, J. ; Komuro, S. ; Hirao, N.
Author_Institution :
AOMEM Center, Tianjin Univ. of Technol. & Educ., Tianjin, China
Abstract :
Mn-doped nanocrystalline ZnO thin films have been formed on SiOx/Si substrates by laser ablation and post annealing. It was shown that the magnetic resistance of the samples strongly depended on the annealing temperature and could be correlated to the carrier density change in the ZnO host crystal and/or the Mn magnetism. It was also shown that some of the fabricated sample showed low temperature ferromagnetism, which arose from the local structure change of Mn ion in the ZnO matrix. Our results show a possibility of realizing the ZnO-based magnetic semiconductor by Mn doping.
Keywords :
Curie temperature; II-VI semiconductors; carrier density; ferromagnetic materials; laser ablation; magnetic annealing; magnetic semiconductors; magnetic structure; magnetic thin films; manganese; nanofabrication; nanomagnetics; nanostructured materials; semiconductor doping; semiconductor thin films; wide band gap semiconductors; zinc compounds; Curie temperature; Mn-doped nanocrystalline thin films; SiOx-Si; ZnO:Mn; carrier density; doping; ferromagnetism; laser ablation; local structure change; magnetic resistance; magnetic semiconductor; post-annealing; Annealing; Doping; Manganese; Zinc oxide; Ferromagnetism; SQUID; XAFS; ZnO:Mn;
Conference_Titel :
Nanotechnology (IEEE-NANO), 2012 12th IEEE Conference on
Conference_Location :
Birmingham
Print_ISBN :
978-1-4673-2198-3
DOI :
10.1109/NANO.2012.6321931
