Title :
Mesoporous activated carbon from amphiphilic carbonaceous material and its application in EDLC
Author :
Wang, Jin ; Chen, Mingming ; Wang, Chengyang ; Zheng, Jiaming
Author_Institution :
Key Lab. for Green Chem. Technol., Tianjin Univ., Tianjin, China
Abstract :
Amphiphilic carbonaceous material (ACM), which could be dispersed in alkaline aqueous solutions in nano-scale, was prepared by oxidation of green needle coke. Mesoporous activated carbon was then obtained by further KOH activation, named as AC-A. It was showed that AC-A was a mesoporous material with surface area and pore volume up to 3347 m2/g and 1.81 cm3/g. For its excellent pore structure and surface characteristics, AC-A was selected as electrode material for Electric double-layer capacitor (EDLC). According to electrochemical tests, AC-A electrode exhibited specific capacitance as high as 348 F/g and also excellent performance under large discharging currents, which was partly attributed to the large specific surface area, high mesoporosity and good surface wettability of the material.
Keywords :
electrochemical electrodes; electrolytic capacitors; mesoporous materials; oxidation; potassium compounds; wetting; AC-A electrode; EDLC; KOH; KOH activation; alkaline aqueous solutions; amphiphilic carbonaceous material; discharging currents; electric double-layer capacitor; electrochemical tests; electrode material; green needle coke; mesoporous activated carbon; mesoporous material; oxidation; pore structure; surface area; surface characteristics; surface wettability; Capacitance; Chemical technology; Electrodes; Mesoporous materials; Needles; Organic materials; Oxidation; Supercapacitors; Surface discharges; X-ray scattering;
Conference_Titel :
Nanoelectronics Conference (INEC), 2010 3rd International
Conference_Location :
Hong Kong
Print_ISBN :
978-1-4244-3543-2
Electronic_ISBN :
978-1-4244-3544-9
DOI :
10.1109/INEC.2010.5424645