Langmuir-Blodgett films of electroactive polymers

Author

Skotheim, T.A. ; Yang, X.Q. ; Chen ; Lee, H.S. ; Okamoto, Y. ; Rubner, M.F.

Author_Institution

Brookhaven Nat. Lab., Upton, NY, USA

fYear

1989

fDate

9-12 Nov 1989

Firstpage

1306

Abstract

Electroactive Langmuir-Blodgett (LB) films have been assembled from mixtures of poly(3-alkyl thiophenes) and stearic acid. Stable monolayers and highly ordered multilayers were formed with varying alkyl chain lengths from four carbons to eighteen carbons. X-ray diffraction revealed that the multilayers form well-defined two-dimensional structures. X-ray absorption experiments revealed that the polythiophene backbone is disordered in a matrix of highly ordered and vertically oriented stearic acid molecules. With long (eighteen carbon) alkyl chains, the chains were oriented along the stearic acid molecules

Keywords

Langmuir-Blodgett films; X-ray absorption; X-ray diffraction examination of materials; polymer blends; polymer films; X-ray absorption experiments; X-ray diffraction; alkyl chain lengths; electroactive Langmuir-Blodgett films; electroactive polymers; highly ordered multilayers; poly 3-alkyl thiophenes; polythiophene backbone; stable monolayers; vertically oriented stearic acid molecules; well-defined two-dimensional structures; Electromagnetic wave absorption; Electrons; Laboratories; Nonhomogeneous media; Optical films; Polymer films; Resonance; Storage rings; Synchrotrons; X-ray diffraction;

fLanguage

English

Publisher

ieee

Conference_Titel

Engineering in Medicine and Biology Society, 1989. Images of the Twenty-First Century., Proceedings of the Annual International Conference of the IEEE Engineering in

Conference_Location

Seattle, WA

Type

conf

DOI

10.1109/IEMBS.1989.96208

Filename

96208