Title :
Numeric reconstruction of a distribution of electrically active defects in PVDF from the thermoluminescence spectra
Author :
Gorokhovatsky, Yu. ; Kunze, P. ; Stark, W. ; Temnov, D.
Author_Institution :
Herzen Pedagogical Univ., St. Petersburg, Russia
Abstract :
In the thermally stimulated luminescence spectrum of PVDF three peaks are found in the temperature range 120 K (γ-peak), 190 K (β-peak) and 320 K (α-peak). The use of numeric methods for experimental results development with the application of the regularization algorithms of Tikhonov (1986) and the method of varying the sample heating rate, allows one to define in a reliable way the parameters of the most probable activation energy and the effective frequency factor of electrically active defects for all relaxation processes in PVDF
Keywords :
defect states; dielectric relaxation; noncrystalline defects; polymers; thermoluminescence; α-peak; β-peak; γ-peak; 120 K; 190 K; 320 K; PVDF; activation energy; effective frequency factor; electrets; electrically active defect distribution; numeric reconstruction; regularization algorithms; relaxation processes; sample heating rate dependence; thermally stimulated luminescence spectrum; thermoluminescence spectra; Charge carriers; Frequency; Heating; Luminescence; Materials reliability; Materials testing; Polyethylene; Polymers; Temperature dependence; Temperature distribution;
Conference_Titel :
Electrets, 1999. ISE 10. Proceedings. 10th International Symposium on
Conference_Location :
Athens
Print_ISBN :
0-7803-5025-1
DOI :
10.1109/ISE.1999.832072