Broadband dielectric metrology for polymer composite films

We evaluated the dielectric permittivity and relaxation in polymer composite films filled with ferroelectric ceramics. Such materials are currently being developed for power-ground decoupling in electronic circuits operating at microwave frequencies. In order to extend the measurements to the microwave range, we developed an appropriate expression for the input admittance of a thin film capacitance terminating a coaxial line. The theoretical model treats the capacitance as a distributed network and correlates the network scattering parameter with complex permittivity of the specimen. The method eliminates the systematic uncertainties of the lumped element approximations and is suitable for high frequency characterization of low impedance substrates with high value of the dielectric constant. The complex permittivity was measured at frequencies of 100 Hz to 10 GHz for films 100 μm thick, having the dielectric constant of 4 to 40, and was fitted to a dielectric model expressed as a combination of Havriliak-Negami functions. An intrinsic high frequency relaxation process has been identified. It was found that the position of the loss peak depends on the relaxation of polymer matrix, while its magnitude is amplified by the permittivity of the ferroelectric component