Title :
Electrodeposited thin-layer electrodes for the use in potentially implantable glucose fuel cells
Author :
Kloke, A. ; Kerzenmacher, S. ; Zengerle, R. ; von Stetten, F.
Author_Institution :
Dept. of Microsyst. Eng., IMTEK Univ. of Freiburg, Freiburg, Germany
Abstract :
We present a novel concept for the fabrication of electrodes to be used in thin-layer implantable glucose fuel cells employing platinum based materials as long-term stable abiotic catalysts. A highly porous anode for glucose oxidation is fabricated by a multiple alternation of electrodeposition of platinum-copper alloy and subsequent electrochemical extraction of the non-noble copper. To form a permeable oxygen reduction cathode, platinum black is deposited onto a gold-coated polycarbonate tracketch membrane (PC-TEM). Power densities of up to 3.1 muW cm-2 are obtained for consequently assembled fuel cells. The novel electrode structures exhibit comparable performance to state of the art at significantly reduced thickness and facilitated fabrication.
Keywords :
copper; electrochemical electrodes; electrodeposition; fuel cells; platinum; Pt-Cu; electrochemical extraction; electrodeposited thin-layer electrodes; glucose oxidation; long-term stable abiotic catalysts; oxygen reduction cathode; polycarbonate track- etch membrane; porous anode; potentially implantable glucose fuel cells; Anodes; Biomembranes; Cathodes; Copper alloys; Electrodes; Fabrication; Fuel cells; Oxidation; Platinum alloys; Sugar; Biofuel Cell; Electrodeposition; Implantable Fuel Cell; Implantable power source; Thin-layer electrodes;
Conference_Titel :
Solid-State Sensors, Actuators and Microsystems Conference, 2009. TRANSDUCERS 2009. International
Conference_Location :
Denver, CO
Print_ISBN :
978-1-4244-4190-7
Electronic_ISBN :
978-1-4244-4193-8
DOI :
10.1109/SENSOR.2009.5285380