Title :
Molding Compounds Adhesion and Influence on Reliability of Plastic Packages for SiC-Based Power MOS Devices
Author :
Scandurra, Antonino ; Indelli, Giuseppe Francesco ; Zafarana, Roberto ; Cavallaro, Andrea ; Scrofani, Emanuele ; Giry, Jean Paul ; Russo, S. ; Bakowski, Mietek
Author_Institution :
Lab. Superfici e Interfasi, Catania, Italy
Abstract :
Adhesion and interface compositions of epoxy phenolic molding compounds (EMCs) for high-temperature plastic packages are studied. Interfaces are obtained by molding two EMCs onto aluminum oxide-hydroxide surfaces (oxide onto thin film of AlSiCu) and two die passivation layers consisting of fluorinated polyimide and cyclotene. One compound (A) is a “green” type, containing organic phosphorous-based flame retardant, and the other compound (B) is a conventional type containing antimony (III) oxide and bromined resin flame retardants. A high-temperature storage test at 250 °C is employed to study chemical modifications occurring at the previously mentioned interfaces. A high-temperature reverse bias test at 225 °C is employed to study the influences of the EMC chemical formulations on the reliability of plastic packages for SiC-based power MOS devices. Green compound A shows poor adhesion onto Al oxide and high adhesion strength onto both polymer passivations. The failure mechanism is mainly cohesive on the polymer passivations. The conventional compound B shows a high degree of delamination because of poor adhesion compared with the green compound. SiC-based power MOS devices assembled in plastic packages with compound A show better reliability under HTRB test at 225 °C compared with compound B.
Keywords :
adhesion; passivation; plastic packaging; silicon compounds; EMC chemical formulation; SiC; adhesion strength; aluminum oxide hydroxide surface; bromined resin flame retardants; chemical modification; cyclotene; delamination; epoxy phenolic molding compound; failure mechanism; fluorinated polyimide; high temperature plastic package; high temperature reverse bias test; high temperature storage test; interface composition; molding compound adhesion; organic phosphorous based flame retardant; passivation layers; plastic package reliability; polymer passivation; power MOS device; temperature 225 C; temperature 250 C; Adhesion; X-ray photoelectron spectroscopy (XPS); green molding compounds; reliability; scanning acoustic microscopy (SAM); silicon carbide devices;
Journal_Title :
Components, Packaging and Manufacturing Technology, IEEE Transactions on
DOI :
10.1109/TCPMT.2013.2247466