Title :
A new, facile synthesis of bis(ethylene)dithiotetrathiafulvalene and related donors for synthetic metals
Author :
Moller, Henry ; Ueba, Yuuki
Author_Institution :
R&D Group, Sumitomo Electric Industries
Abstract :
Summary form only given. Bis(ethylene)dithiotetrathiafulvalene (BEDT-TTF), bis(oxybis(methylenethio))tetrathiafulvalene (BOBMT-TTF) and bis-(thiobis(methylenethio))tetrathiafulvalene (BTBMT-TTF) and related donors were prepared in two steps starting from 1,3,4,6-tetrathiapentalene-2,5-dione (thiapendione) via the intermediate 4,5-dimercapto-1,3-dithiol-2-one. The reaction conditions for and the mechanism of the basic cleavage of thiapendione are briefly discussed.
Keywords :
Chemistry; Conductors; Crystals; Metals industry; Research and development; Superconductivity; Synchrotron radiation;
Conference_Titel :
Science and Technology of Synthetic Metals, 1994. ICSM '94. International Conference on
Conference_Location :
Seoul, Korea
DOI :
10.1109/STSM.1994.834908
