Title :
Hybrid composites of polyamide-imide and silica applied to wire insulation
Author :
Mesaki, Masakazu ; Goda, Hideki
Author_Institution :
The Furukawa Electr. Co., Ltd, Kanagawa, Japan
Abstract :
Aromatic polyamide-imide resins (PAI) based on trimellitic anhydride and diphenylmethane-4,4´-diisocyanete, were modified by an oligo-alkoxysilane compound to lead to novel silane-modified PAIs. Then, PAI-silica hybrid films were prepared by drying and curing the silane-modified PAIs. With increasing silica unit content, the hybrid films have higher elastic modulus and tensile strength of the original PAI film, however maintain maximum elongation. Furthermore, they have much lower moisture absorption than the PAI film under wet conditions. Moreover, this hybrid film found that a difference was in a dielectric constant as compared with the usual film. This report describes the characteristic about the enameled wire used for the silane-modified PAI varnish as an insulation layer
Keywords :
absorption; elongation; insulated wires; organic insulating materials; permittivity; polymers; silicon compounds; varnish; PAI-silica hybrid films; aromatic polyamide-imide resins; curing; dielectric constant; diphenylmethane-4,4´-diisocyanete; drying; elastic modulus; elongation; enameled wire; insulation layer; lower moisture absorption; oligo-alkoxysilane compound; silane-modified PAI varnish; silica unit content; tensile strength; trimellitic anhydride; wet condition; Absorption; Cable insulation; Curing; Dielectric constant; Dielectrics and electrical insulation; Lead compounds; Moisture; Resins; Silicon compounds; Wire;
Conference_Titel :
Electrical Insulation Conference and Electrical Manufacturing & Coil Winding Conference, 2001. Proceedings
Conference_Location :
Cincinnati, OH
Print_ISBN :
0-7803-7180-1
DOI :
10.1109/EEIC.2001.965580