• DocumentCode
    1919854
  • Title

    Preparation of high-value chemicals from selective fast pyrolysis of bamboo directionally catalyzed by phosphoric acid

  • Author

    Liu, Junli ; Jiang, Jianchun ; Huang, Haitao

  • Author_Institution
    Key Lab. of Biomass Energy & Mater., Inst. of Chem. Ind. of Forestry Products, Nanjing, China
  • Volume
    1
  • fYear
    2011
  • fDate
    20-22 May 2011
  • Firstpage
    479
  • Lastpage
    484
  • Abstract
    Bamboo is an abundant plant as the feedstock of biomass energy in many countries all over the world. It has an extremely rapid growing rate, and it can be considered as a sustainable raw material wood resource. In this study, high-value chemicals such as furfural, levoglucosenone, 2,3-dihydro benzofuran and levoglucosan, prepared from bamboo by directionally selective fast pyrolysis of phosphoric acid catalyst were investigated by curie-point pyrolysis-gas chromatography-mass spectroscopy (CP-GC-MS). It is a very effective method of selective pyrolysis bamboo catalyzed by H3PO4 to reduce the content of the phenolic compounds and enhance the content of sugar and furan compounds. It was resulted from enhancing the depolymerization of cellulose and promoting the formation of solid char from lignin and preventing the formation of the phenolic compounds. The content of the major sugar compounds reached to 50% along with the use of catalyst. The content of the major furan compounds enhanced, mostly the increase of fufural.
  • Keywords
    chemical engineering; chromatography; materials preparation; pyrolysis; raw materials; renewable energy sources; wood; H3PO4; bamboo; biomass energy; curie point pyrolysis gas chromatography mass spectroscopy; depolymerization enhancement; dihydro benzofuran; furan compounds; furfural; high value chemical preparation; high value chemicals; levoglucosan; levoglucosenone; phenolic compounds; phosphoric acid; phosphoric acid catalyst; rapid growing rate; selective fast pyrolysis; selective pyrolysis bamboo; sustainable raw material wood resource; Chemicals; Compounds; Iron; Production; Solids; Zinc; Bamboo; high-value chemicals; selective pyrolysis;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Materials for Renewable Energy & Environment (ICMREE), 2011 International Conference on
  • Conference_Location
    Shanghai
  • Print_ISBN
    978-1-61284-749-8
  • Type

    conf

  • DOI
    10.1109/ICMREE.2011.5930856
  • Filename
    5930856