Title :
The mechanism of low temperature sintering PZT ceramics with additives of Li2O-Bi2O3-CdO
Author :
Wang, Kiaoxing ; Lu, Peiwen ; Shen, Dawei ; Zue, W. ; Zhao, Neiyu
Author_Institution :
Dept. of Silicate Eng., Nanjing Inst. of Chem. Technol., China
fDate :
30 Aug-2 Sep 1992
Abstract :
The effects of Li2O, Bi2O3, CdO, and V2O5 on sintering temperature and electromechanical properties were investigated for PZT (lead zirconate titanate) ceramics. In order to reduce the sintering temperatures further, complex additives of Li2O-Bi2O3-CdO (LBC) were employed. LBC will melt to form liquid at low temperature and promote the densification of the ceramics. The mass transport process of the solution and reprecipitation made the element distribution uniform and led to further densification of the ceramics. The electromechanical properties of the PZT ceramics were not affected because the additives did not have harmful impurities
Keywords :
ceramics; dielectric losses; grain boundaries; lead compounds; piezoelectric materials; scanning electron microscope examination of materials; scanning-transmission electron microscope examination of materials; sintering; Li2O-Bi2O3-CdO; PZT ceramics; PbZrO3TiO3; SEM; STEM; V2O5; ceramic densification; electromechanical properties; grain boundary; loss tangent; low temperature sintering mechanism; mass transport process; reprecipitation; sintering temperature; Additives; Ceramics; Chemical technology; Erbium; Impedance; Mechanical factors; Pollution measurement; Temperature;
Conference_Titel :
Applications of Ferroelectrics, 1992. ISAF '92., Proceedings of the Eighth IEEE International Symposium on
Conference_Location :
Greenville, SC
Print_ISBN :
0-7803-0465-9
DOI :
10.1109/ISAF.1992.300731