Title :
Surface and optical properties of nanohybrid PMMA/TiO2 coated glass surface: The effect of molar ratios of PMMA: TiO2 solution
Author :
Achoi, M.F. ; Aziz, Nor Azlina Ab ; Hafizah, N.N. ; Amalina, M.N. ; Asiah, M.N. ; Rusop, M. ; Abdullah, Saad
Author_Institution :
Fac. of Appl. Sci., Univ. Teknol. MARA, Shah Alam, Malaysia
Abstract :
Preparation of nanohybrid PMMA/TiO2 hybrid was reported by using sol-gel spin-coating method. This studied involve modification optical band gap energy of TiO2 at different molar concentration of TTIB precursor. Field emission scanning electron microscope (FESEM) results showed TiO2 particles encapsulate surroundings big size of PMMA particles. This existence of board particles have been confirmed using energy dispersive analysis x-ray (EDAX) spectrum. We have found the atomic force microscopy (AFM) surface morphology result for sample at (1:100) 0.005M precursor molar concentration has matrix of PMMA encapsulated TiO2 particles. From ultraviolet-visible-near infrared (UV-Vis-NiR) spectroscope, we have found as increase of TTiB precursor molar ratios in PMMA solution, the transmittance properties of nanohybrid PMMA/TiO2 was increased from 44.24 to 77.39% in visible region. This study suggested for improvement of TiO2 surface and optical properties coated glass surface.
Keywords :
X-ray chemical analysis; atomic force microscopy; energy gap; field emission electron microscopy; filled polymers; infrared spectra; nanocomposites; nanofabrication; optical constants; particle reinforced composites; particle size; scanning electron microscopy; semiconductor materials; sol-gel processing; spin coating; surface morphology; titanium compounds; ultraviolet spectra; visible spectra; AFM; EDAX; FESEM; PMMA particles; SiO2; TiO2; atomic force microscopy; energy dispersive analysis X-ray spectrum; field emission scanning electron microscopy; molar concentration; nanohybrid coated glass surface; optical band gap energy; optical properties; particle size; sol-gel spin-coating method; surface morphology; surface properties; transmittance properties; ultraviolet-visible-near infrared spectroscopy; PMMA/TiO2; TTiB; nanohybrid; optical band gap energy;
Conference_Titel :
Humanities, Science and Engineering (CHUSER), 2012 IEEE Colloquium on
Conference_Location :
Kota Kinabalu
Print_ISBN :
978-1-4673-4615-3
DOI :
10.1109/CHUSER.2012.6504433